Some standard my.cnf variants can be found at /Applications/MAMP/Library/support-files/
Invoking mysqld --verbose --help | less on the MAMP mysqld binary reports:
Default options are read from the following files in the given order:
/etc/my.cnf /etc/mysql/my.cnf /Applications/MAMP/conf/my.cnf ~/.my.cnf
Copy one of the variants in /Applications/MAMP/Library/support-files/ to one of the locations in mysqld's search order above, and you should be good to go after restarting the daemon.
I found that MAMP PRO will create a my.cnf by default on startup under the MAMP/tmp directory if a ~/my.cnf is not provided ... grepping ps aux you may find the default location under /Applications/MAMP/tmp/my.cnf ...