Use :map! and :map for manually set keys and :help 'char(-combination)' to find out which keys are already mapped in vim out-of-the-box(/out of your specific compiling options).
(Slightly off-topic but still regardable (I think): Use :scriptnames to see which files have been sourced in which order.)
The first command displays the maps that work in normal, visual and
select and operator pending mode. The second command displays the maps
that work in insert and command-line mode.
Typically the output of the above commands will span several pages.
You can use the following set of commands to redirect the output to
the vim_maps.txt file: