You'll also need to ensure both side have the same collation to avoid errors or further coercions if you want to compare against a table variable or temp table varchar column
and because the constant value will have the collation of the database Update: only for local variables, not for constants nope, not even then
SELECT *
FROM Venue
WHERE
Name COLLATE Latin1_general_CI_AI Like '%cafe%' COLLATE Latin1_general_CI_AI