64位程序是否比32位版本更大更快？

Regardless of the benefits, I would suggest that you always compile your program for the system's default word size (32-bit or 64-bit), since if you compile a library as a 32-bit binary and provide it on a 64-bit system, you will force anyone who wants to link with your library to provide their library (and any other library dependencies) as a 32-bit binary, when the 64-bit version is the default available. This can be quite a nuisance for everyone. When in doubt, provide both versions of your library.

As to the practical benefits of 64-bit... the most obvious is that you get a bigger address space, so if mmap a file, you can address more of it at once (and load larger files into memory). Another benefit is that, assuming the compiler does a good job of optimizing, many of your arithmetic operations can be parallelized (for example, placing two pairs of 32-bit numbers in two registers and performing two adds in single add operation), and big number computations will run more quickly. That said, the whole 64-bit vs 32-bit thing won't help you with asymptotic complexity at all, so if you are looking to optimize your code, you should probably be looking at the algorithms rather than the constant factors like this.

EDIT:
Please disregard my statement about the parallelized addition. This is not performed by an ordinary add statement... I was confusing that with some of the vectorized/SSE instructions. A more accurate benefit, aside from the larger address space, is that there are more general purpose registers, which means more local variables can be maintained in the CPU register file, which is much faster to access, than if you place the variables in the program stack (which usually means going out to the L1 cache).

Unless you need to access more memory that 32b addressing will allow you, the benefits will be small, if any.

When running on 64b CPU, you get the same memory interface no matter if you are running 32b or 64b code (you are using the same cache and same BUS).

While x64 architecture has a few more registers which allows easier optimizations, this is often counteracted by the fact pointers are now larger and using any structures with pointers results in a higher memory traffic. I would estimate the increase in the overall memory usage for a 64b application compared to a 32b one to be around 15-30 %.

In the specific case of x68 to x68_64, the 64 bit program will be about the same size, if not slightly smaller, use a bit more memory, and run faster. Mostly this is because x86_64 doesn't just have 64 bit registers, it also has twice as many. x86 does not have enough registers to make compiled languages as efficient as they could be, so x86 code spends a lot of instructions and memory bandwidth shifting data back and forth between registers and memory. x86_64 has much less of that, and so it takes a little less space and runs faster. Floating point and bit-twiddling vector instructions are also much more efficient in x86_64.

In general, though, 64 bit code is not necessarily any faster, and is usually larger, both for code and memory usage at runtime.

I typically see a 30% speed improvement for compute-intensive code on x86-64 compared to x86. This is most likely due to the fact that we have 16 x 64 bit general purpose registers and 16 x SSE registers instead of 8 x 32 bit general purpose registers and 8 x SSE registers. This is with the Intel ICC compiler (11.1) on an x86-64 Linux - results with other compilers (e.g. gcc), or with other operating systems (e.g. Windows), may be different of course.

Only justification for moving your application to 64 bit is need for more memory in applications like large databases or ERP applications with at least 100s of concurrent users where 2 GB limit will be exceeded fairly quickly when applications cache for better performance. This is case specially on Windows OS where integer and long is still 32 bit (they have new variable _int64. Only pointers are 64 bit. In fact WOW64 is highly optimised on Windows x64 so that 32 bit applications run with low penalty on 64 bit Windows OS. My experience on Windows x64 is 32 bit application version run 10-15% faster than 64 bit since in former case at least for proprietary memory databases you can use pointer arithmatic for maintaining b-tree (most processor intensive part of database systems). Compuatation intensive applications which require large decimals for highest accuracy not afforded by double on 32-64 bit operating system. These applications can use _int64 in natively instead of software emulation. Of course large disk based databases will also show improvement over 32 bit simply due to ability to use large memory for caching query plans and so on.

In addition to having more registers, 64-bit has SSE2 by default. This means that you can indeed perform some calculations in parallel. The SSE extensions had other goodies too. But I guess the main benefit is not having to check for the presence of the extensions. If it's x64, it has SSE2 available. ...If my memory serves me correctly.

Any applications that require CPU usage such as transcoding, display performance and media rendering, whether it be audio or visual, will certainly require (at this point) and benefit from using 64 bit versus 32 bit due to the CPU's ability to deal with the sheer amount of data being thrown at it. It's not so much a question of address space as it is the way the data is being dealt with. A 64 bit processor, given 64 bit code, is going to perform better, especially with mathematically difficult things like transcoding and VoIP data - in fact, any sort of 'math' applications should benefit by the usage of 64 bit CPUs and operating systems. Prove me wrong.

I'm coding a chess engine named foolsmate. The best move extraction using a minimax-based tree search to depth 9 (from a certain position) took:

on Win32 configuration: ~17.0s;

after switching to x64 configuration: ~10.3s;

This is 41% of acceleration!

On my machine, same h265 encode works almost twice as fast using virtulDub_x64 (with x64 h265 library) vs virtulDub_x32 (regular x32 h265 library). That's probably because longint (64bits) numbers operations (ie: add) can be done on a single instruction on x64, but on 32bit needs two: add lower part, and then add (with carry) the higher part. So unless integer maths are limited to 32bit integers, most of it will take more time under x32.