It's not possible for them to arrive in your application out of order. Anything can happen on the network, but TCP will only present you the bytes in the order they were sent.
WebSocket runs over TCP, so on that level @EJP 's answer applies. WebSocket can be "intercepted" by intermediaries (like WS proxies): those are allowed to reorder WebSocket control frames (i.e. WS pings/pongs), but not message frames when no WebSocket extension is in place. If there is a neogiated extension in place that in principle allows reordering, then an intermediary may only do so if it understands the extension and the reordering rules that apply.
At the network layer TCP is suppose to guarantee that messages arrive in order. At the application layer, errors can occur in the code and cause your messages to be out of order in the logic of your code. It could be the network stack your application is using or your application code itself.
If you asked me, can my Node.js application guarantee sending and receiving messages in order? I'm going to have to say no. I've run websocket applications connected to WiFi under high latency and low signal. It causes very strange behavior as if packets are dropped and messages are out of sequence.